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Published on: July 20, 2022
Mixed-valent Mn supertetrahedra and planar discs as enhanced magnetic coolers
Maria Manoli1, Anna Collins, Simon Parsons
1School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ UK.
Abstract:
The syntheses and structures of two decametallic mixed-valent Mn supertetrahedra using 2-amino-2-methyl-1,3-propanediol (ampH2), two decametallic mixed-valent Mn planar discs using 2-amino-2-methyl-1,3-propanediol (ampH2) and 2-amino-2-ethyl-1,3-propanediol (aepH2), and a tetradecametallic mixed-valent Mn planar disc using pentaerythritol (H4peol) are reported. The decametallic complexes display dominant ferromagnetic exchange and spin ground states of S = 22, and the tetradecametallic complex displays dominant antiferromagnetic exchange and a spin ground state of S = 7 +/- 1. All display large (the former) and enormous (the latter) magnetocaloric effect--the former as a result of negligible zero-field splitting of the ground state, and the latter as a result of possessing a high spin-degeneracy at finite low temperatures--making them the very best cooling refrigerants for low-temperature applications.
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