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Related Concept Videos

Susceptibility, Permittivity and Dielectric Constant01:26

Susceptibility, Permittivity and Dielectric Constant

When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
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The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
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Concurrent Quantitative Conductivity and Mechanical Properties Measurements of Organic Photovoltaic Materials using AFM
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Published on: January 23, 2013

Correlation between dielectric/organic interface properties and key electrical parameters in PPV-based OFETs.

Francesco Todescato1, Raffaella Capelli, Franco Dinelli

  • 1Consiglio Nazionale delle Ricerche (CNR), Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), via P. Gobetti 101, I-40129 Bologna, Italy. f.todescato@bo.ismn.cnr.it

The Journal of Physical Chemistry. B
|July 30, 2008
PubMed
Summary

Optimizing dielectric/organic interfaces significantly enhances field-effect transistor performance. Surface treatments that eliminate OH groups boost hole mobility and reduce hysteresis in polyphenylenevinylene (PPV) transistors.

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Area of Science:

  • Organic electronics
  • Materials science
  • Semiconductor physics

Background:

  • Field-effect transistors (FETs) are crucial electronic components.
  • Polyphenylenevinylene (PPV) derivatives are promising organic semiconductors.
  • Dielectric-semiconductor interface properties critically influence FET performance.

Purpose of the Study:

  • To investigate the impact of dielectric surface treatments on PPV-based FET electrical characteristics.
  • To establish correlations between interface properties and device performance parameters.
  • To identify optimal surface modifications for improved FET behavior.

Main Methods:

  • Systematic investigation of common dielectric surface treatments (e.g., silane treatments, polymer layers).
  • Electrical characterization of PPV-based FETs, measuring charge carrier mobility, On/Off ratio, threshold voltage, and hysteresis.
  • Analysis of dielectric surface properties, focusing on OH group density and molecular interactions.

Main Results:

  • Presence of OH groups on dielectric surfaces decreases hole mobility.
  • Octadecyltrichlorosilane (OTS) and hexamethyldisilazane (HMDS) treatments improve hole mobility and reduce current hysteresis.
  • Eliminating OH groups via polymer dielectrics yields performance comparable to HMDS treatment.
  • Achieved highest reported hole mobility values for PPV-based FETs using HMDS and polymer dielectrics.

Conclusions:

  • Dielectric surface properties, particularly OH group density and interfacial interactions, profoundly affect PPV-based FET performance.
  • Specific surface treatments like HMDS and polymer dielectrics are highly effective in enhancing charge carrier mobility and device stability.
  • This study provides a pathway for designing high-performance organic field-effect transistors.