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Synthesis and Functionalization of 3D Nano-graphene Materials: Graphene Aerogels and Graphene Macro Assemblies
Published on: November 5, 2015
Ionothermal synthesis of crystalline, condensed, graphitic carbon nitride
Michael J Bojdys1, Jens-Oliver Müller, Markus Antonietti
1Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476 Potsdam/Golm, Germany.
Abstract:
Herein we report the synthesis of a crystalline graphitic carbon nitride, or g-C(3)N(4), obtained from the temperature-induced condensation of dicyandiamide (NH(2)C(=NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g-C(3)N(4) species is based on sheets of hexagonally arranged s-heptazine (C(6)N(7)) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X-ray diffractometry and high-resolution transmission electron microscopy.
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