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Updated: Jul 3, 2026

Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
Published on: November 30, 2022
Hydrogenation of molecular cyclic diborane4 compounds featuring B-B bonds and olefinic or aromatic bridges: a quantum
F Allouti1, W Siebert, H-J Himmel
1Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany.
Abstract:
Hydrogenation reactions starting with di- or oligonuclear boron compounds featuring direct B-B bonds with the B atoms in the formal oxidation state +II are analyzed with the aid of ab initio quantum chemical (RI-MP2) calculations. The products of these reactions are B(III) hydrides which might be useful starting reagents for stoichiometric hydrogenation reactions and possibly in special cases also for hydrogen storage. Several different isomers of these B(III) hydrides featuring either terminal or bridging H atoms were considered. The results are compared to hydrogenation reactions of related molecules.
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