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Updated: Jul 3, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
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Facile intramolecular C(sp3)-H bond activation with PdII

Martin Bröring1, Christian Kleeberg

  • 1Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany. Martin.Broering@chemie.uni-marburg.de

Chemical Communications (Cambridge, England)
|August 9, 2008
PubMed
Summary

The reaction of bis(4-tert-butylthiazolyl)isoindoline with palladium acetate exclusively forms an organometallic PdII compound. This compound features a C-H activated t-butyl group and a cis-positioned, hemilabile S-coordinated thiazole donor.

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