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Updated: Jul 2, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Ligand influence on the formation of P/Se semiconductor materials from metal-organic complexes
Arunkumar Panneerselvam1, Chinh Q Nguyen, John Waters
1The School of Chemistry and The School of Materials, The University of Manchester, Oxford Road, Manchester, UKM13 9PL.
Abstract:
The complexes [Ni{(SeP(i)Pr(2))(2)N}(2)] (2), [Ni(Se(2)P(i)Pr(2))(2)] (), and [Co(Se(2)P(i)Pr(2))(2)] (4) were synthesised and the X-ray single crystal structures of (1) and (2) were determined. Thin films of nickel selenide, cobalt selenide and cobalt phosphide have been deposited by the chemical vapour deposition method using imidodiselenophosphinato-nickel(ii) (1), -cobalt(ii) [Co{(SeP(i)Pr(2))(2)N}(2)] (3), diselenophosphinato-nickel(ii) (2), -cobalt(ii) (4) and diselenocarbamato-nickel(ii) [Ni(Se(2)CNEt(2))(2)] (5), and -cobalt(iii) [Co(Se(2)CNEt(2))(3)] (6) precursors.
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