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Programmable digital pulse generator for proton enhanced (13)C high resolution NMR in solids
1Department of Physical Chemistry, University of Nymegen, Toernooiveld, 6525 ED Nymegen, The Netherlands.
The Review of Scientific Instruments
|April 1, 1979
Summary
A new programmable pulse generator for Nuclear Magnetic Resonance (NMR) spectrometers offers flexible pulse sequencing. It supports single and double cycle modes for advanced NMR experiments, enhancing experimental capabilities.
Area of Science:
- Analytical Chemistry
- Spectroscopy
- Physical Chemistry
Background:
- Nuclear Magnetic Resonance (NMR) spectroscopy is a powerful technique for molecular structure determination.
- Precise control over pulse sequences is crucial for advanced NMR experiments.
- Existing pulse generators may have limitations in flexibility and programmability.
Purpose of the Study:
- To introduce a novel programmable pulse generator for NMR spectrometers.
- To enhance the flexibility and control of pulse sequences in NMR experiments.
- To demonstrate the utility of the generator in complex NMR experiments.
Main Methods:
- The described pulse generator operates in two modes: single cycle and double cycle.
- Single cycle mode allows sequential execution of up to 16 pulses.
- Double cycle mode enables programmable repetition (n times, n<=99) of a subset of pulses (<=15).
- Pulse lengths are programmable manually or via computer control.
Main Results:
- The pulse generator offers versatile pulse sequencing capabilities.
- It facilitates the execution of complex pulse sequences required for advanced NMR experiments.
- Successful programming for a multiple contact proton-enhanced (13)C NMR experiment was demonstrated.
Conclusions:
- The developed programmable pulse generator provides enhanced control over NMR experiments.
- Its flexible operating modes and programmability make it suitable for sophisticated NMR applications.
- This tool can advance the capabilities of NMR spectroscopy for various research fields.
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