Nanoscale Ru(0) particles: arene hydrogenation catalysts in imidazolium ionic liquids
Martin H G Prechtl1, Morgana Scariot, Jackson D Scholten
1Laboratory of Molecular Catalysis, Institute of Chemistry, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves 9500, Porto Alegre, CEP 91501-970, RS, Brazil.
Abstract:
The reduction of [Ru(COD)(2-methylallyl) 2] (COD = 1,5-cyclooctadiene) dispersed in various room-temperature ionic liquids (ILs), namely, 1- n-butyl-3-methylimidazolium (BMI) and 1- n-decyl-3-methylimidazolium (DMI), associated with the N-bis(trifluoromethanesulfonyl)imidates (NTf 2) and the corresponding tetrafluoroborates (BF 4) with hydrogen gas (4 bar) at 50 degrees C leads to well-dispersed immobilized nanoparticles. Transmission electron microscopy (TEM) analysis of the particles dispersed in the ionic liquid shows the presence of [Ru(0)] n nanoparticles (Ru-NPs) of 2.1-3.5 nm in diameter. Nanoparticles with a smaller mean diameter were obtained in the ILs containing the less coordinating anion (NTf 2) than that in the tetrafluoroborate analogues. The ruthenium nanoparticles in ionic liquids were used for liquid-liquid biphasic hydrogenation of arenes under mild reaction conditions (50-90 degrees C and 4 bar). The apparent activation energy of E A = 42.0 kJ mol (-1) was estimated for the hydrogenation of toluene in the biphasic liquid-liquid system with Ru-NPs/BMI.NTf 2. TEM analysis of the ionic liquid material after the hydrogenation reactions shows no significant agglomeration of the [Ru(0)] n nanoparticles. The catalyst ionic liquid phase can be reused several times without a significant loss in catalytic activity.
More Related Videos
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
10:19Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
Related Concept Videos
02:17Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
02:13Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...