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The de Broglie Wavelength02:32

The de Broglie Wavelength

In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
The Quantum-Mechanical Model of an Atom02:45

The Quantum-Mechanical Model of an Atom

Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra. Schrödinger...
The Bohr Model02:18

The Bohr Model

Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as the nucleus...
The Uncertainty Principle04:08

The Uncertainty Principle

Werner Heisenberg considered the limits of how accurately one can measure properties of an electron or other microscopic particles. He determined that there is a fundamental limit to how accurately one can measure both a particle’s position and its momentum simultaneously. The more accurate the measurement of the momentum of a particle is known, the less accurate the position at that time is known and vice versa. This is what is now called the Heisenberg uncertainty principle. He mathematically...
The Wave Nature of Light02:12

The Wave Nature of Light

The nature of light has been a subject of inquiry since antiquity. In the seventeenth century, Isaac Newton performed experiments with lenses and prisms and was able to demonstrate that white light consists of the individual colors of the rainbow combined together. Newton explained his optics findings in terms of a "corpuscular" view of light, in which light was composed of streams of extremely tiny particles traveling at high speeds according to Newton's laws of motion.
Equilibrium Conditions for a Particle01:23

Equilibrium Conditions for a Particle

When an object is in equilibrium, it is either at rest or moving with a constant velocity. There are two types of equilibrium: static and dynamic. Static equilibrium occurs when an object is at rest, while dynamic equilibrium occurs when an object is moving with a constant velocity. In both cases, there must be a balance of forces acting on the object.
To understand the concept of equilibrium, let us first consider the forces acting on an object. When different forces act on an object, they can...

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Related Experiment Video

Updated: Jul 2, 2026

Direct Imaging of Laser-driven Ultrafast Molecular Rotation
10:52

Direct Imaging of Laser-driven Ultrafast Molecular Rotation

Published on: February 4, 2017

Stroboscopic wave-packet description of nonequilibrium many-electron problems.

P Bokes1, F Corsetti, R W Godby

  • 1Department of Physics, University of York, Heslington, York YO10 5DD, United Kingdom. peter.bokes@stuba.sk

Physical Review Letters
|September 4, 2008
PubMed
Summary

We developed a new orthogonal wave-packet basis set for describing electronic systems out of equilibrium. This method offers new insights and reliable calculations for quantum transport and spin accumulation phenomena.

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Area of Science:

  • Condensed matter physics
  • Quantum mechanics
  • Materials science

Background:

  • Describing nonequilibrium electronic systems is computationally challenging.
  • Existing methods struggle with time-dependent and steady-state phenomena.
  • Accurate calculation of many-electron quantities is crucial.

Purpose of the Study:

  • Introduce an orthogonal wave-packet basis set for efficient description of nonequilibrium extended electronic systems.
  • Provide insight into time-dependent and steady-state nonequilibrium processes.
  • Enable reliable physical estimates of many-electron quantities.

Main Methods:

  • Construction of an orthogonal wave-packet basis set.
  • Utilizing the concept of stroboscopic time propagation.
  • Application to quantum transport and spin accumulation problems.

Main Results:

  • The new basis set offers three desirable properties for enhanced description.
  • Significant insights into nonequilibrium processes were gained.
  • Reliable estimates for density, current, and spin polarization were obtained.
  • New results for time-dependent bias switching and current-induced spin accumulation were achieved.

Conclusions:

  • The orthogonal wave-packet basis set is a powerful tool for studying nonequilibrium electronic systems.
  • This approach advances the understanding of quantum transport and spin-related phenomena.
  • The method provides a reliable framework for theoretical and computational investigations.