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Related Concept Videos

Atomic Nuclei: Types of Nuclear Relaxation01:28

Atomic Nuclei: Types of Nuclear Relaxation

Nuclear relaxation restores the equilibrium population imbalance and can occur via spin–lattice or spin–spin mechanisms, which are first-order exponential decay processes.
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis. This...
NMR Spectroscopy: Spin–Spin Coupling01:08

NMR Spectroscopy: Spin–Spin Coupling

The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved in...
Atomic Nuclei: Nuclear Spin State Overview01:03

Atomic Nuclei: Nuclear Spin State Overview

NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...

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Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities
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Anisotropic spin relaxation in graphene.

N Tombros1, S Tanabe, A Veligura

  • 1Physics of Nanodevices, Nijenborgh 4, 9747 AG Groningen, The Netherlands.

Physical Review Letters
|September 4, 2008
PubMed
Summary

This study reveals that spin relaxation in graphene is significantly faster for spins oriented perpendicular to the graphene layer compared to those parallel to it. This finding impacts the understanding of spin dynamics in graphene spin valve devices.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Spintronics

Background:

  • Spin relaxation is a critical factor limiting spin lifetimes in spintronic devices.
  • Graphene's unique electronic properties make it a promising material for spintronics, but understanding spin relaxation mechanisms is essential for device applications.

Purpose of the Study:

  • To investigate spin relaxation dynamics in graphene using electrical spin valve devices.
  • To compare spin relaxation times for spins injected parallel versus perpendicular to the graphene layer.

Main Methods:

  • Utilized nonlocal geometry electrical graphene spin valve devices.
  • Applied magnetic fields perpendicular to the graphene layer to induce Hanle spin precession.
  • Varied magnetic field strength to control spin injection direction (in-plane vs. out-of-plane magnetization).

Main Results:

  • Observed a 20% decrease in spin relaxation time for spins injected perpendicular to the graphene layer compared to parallel injection.
  • Demonstrated that spin relaxation is more pronounced for out-of-plane spin orientations.

Conclusions:

  • Spin relaxation in graphene is anisotropic, with faster relaxation for out-of-plane spins.
  • The findings suggest differing contributions of spin-orbit interaction mechanisms (Elliott-Yafet and Dyakonov-Perel) for in-plane and out-of-plane spin orientations.