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Updated: Jun 30, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

Ynol ethers from dichloroenol ethers: mechanistic elucidation through 35Cl labeling.

Benjamin Darses1, Anne Milet, Christian Philouze

  • 1Département de Chimie Moléculaire (SERCO), Université Joseph Fourier, UMR-5250, ICMG FR-2607, CNRS BP 53, 38041 Grenoble Cedex 9, France.

Organic Letters
|September 19, 2008
PubMed
Summary

The Fritsch-Buttenberg-Wichell rearrangement and beta-elimination mechanisms were studied for ynol ether formation from dichloroenol ethers. This research clarifies the key pathways in this long-standing chemical transformation.

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