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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
[Bi5(dpd)6 within CH3CN](ClO4)3.3CH3CN: a supramolecular, tetrahedral pentabismuth cluster derived from a nonabismuth
John H Thurston1, Michael J Dougherty, Dale C Swenson
1Department of Chemistry, The University of Iowa, Iowa City, IA 52242, USA.
Abstract:
The novel tetrahedral [Bi(5)(dpd)(6) within CH(3)CN](ClO(4))(3).3CH(3)CN (dpd = di-2-pyridyl-gem-diolate) has been synthesized from [Bi(9)(mu(3)-O)(8)(mu(3)-OH)(6)](ClO(4))(5) and di-2-pyridyl ketone. The Bi(5) complex incorporates CH(3)CN via C-HO hydrogen bonding.
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