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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Two-coordinate d9 complexes. synthesis and oxidation of NHC nickel(I) amides

Carl A Laskowski1, Gregory L Hillhouse

  • 1Gordon Center for Integrative Science, Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA.

Journal of the American Chemical Society
|September 27, 2008
PubMed

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In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
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