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Target-aimed synthesis of anion-deficient perovskites
Evgeny V Antipov1, Artem M Abakumov, Sergey Ya Istomin
1Department of Chemistry, Moscow State University, Moscow 119991, Russia.
Inorganic Chemistry
|September 30, 2008
Abstract:
The brownmillerite-type A 2B 2O 5 structure is considered as a parent one, giving rise to different derivatives: layered double perovskites, A-site and anion-vacancy-ordered perovskites, and the perovskite-like compounds with crystallographic shear planes. The structural relationships and synthesis pathways for these classes of materials are discussed with particular attention to the ordering at the A or B sublattices, anion vacancy ordering, and their mutual interaction.
