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N2 hydrogenation from activated end-on bis(indenyl) zirconium dinitrogen complexes

Doris Pun1, Christopher A Bradley, Emil Lobkovsky

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.

Journal of the American Chemical Society
|October 2, 2008
PubMed
Summary

Researchers synthesized novel end-on dinitrogen zirconocene complexes via sodium amalgam reduction. These complexes undergo hydrogenation to form hydrido zirconocene hydrazido compounds, showcasing a new pathway for dinitrogen activation.

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