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One-pot synthesis of a shape-persistent endo-functionalised nano-sized adamantoid compound

Michael Mastalerz1

  • 1Ulm University, Institute of Organic Chemistry II and Advanced Materials, Albert-Einstein-Allee 11, D-89081 Ulm, Germany. michael.mastalerz@uni-ulm.de

Chemical Communications (Cambridge, England)
|October 3, 2008
PubMed

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...