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Updated: Jun 29, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
Active sites in a two-step catalytic bimolecular reaction on a reconstructed platinum surface
1Catalysis Research Center, Hokkaido University, Sapporo 001-0021, Japan. yama@cat.hokudai.ac.jp
Abstract:
Active sites for a thermally induced bimolecular two-step catalytic reaction (O2-->2O, O + CO-->CO2) that occurs on a Pt(113)(1 x 2) structure at around 160 K were studied by angular distribution measurements of desorbing product CO2. It was found that the intrinsic activity level of two-atom-wide (001) facets is significantly higher than that of two-atom-wide (111) facets, while the activity of (111) facets was also significant when this reaction was induced by irradiation of 193 nm photons. Possible mechanisms for the difference in activities of the two facets are discussed.
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