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Molybdenum tris(2,5-dimethylpyrrolide), a rare homoleptic molybdenum(III) monomer

Keith M Wampler1, Richard R Schrock

  • 1Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Inorganic Chemistry
|October 18, 2008
PubMed

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Structural Isomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...