Related Experiment Video

Updated: Jun 28, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
10:52

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

Estimation of dissociation energy in donor-acceptor complex AuCl x PPh3 via topological analysis of the experimental

Alexandra O Borissova, Alexander A Korlyukov, Mikhail Yu Antipin

    The Journal of Physical Chemistry. A
    |October 31, 2008
    PubMed

    More Related Videos

    Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry16:11

    Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry

    Published on: June 8, 2022

    Förster Resonance Energy Transfer Mapping: A New Methodology to Elucidate Global Structural Features07:09

    Förster Resonance Energy Transfer Mapping: A New Methodology to Elucidate Global Structural Features

    Published on: March 16, 2022

    Related Concept Videos

    Crystal Field Theory - Octahedral Complexes02:58

    Crystal Field Theory - Octahedral Complexes

    Crystal Field Theory
    To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
    CFT focuses on...
    π Molecular Orbitals of the Allyl Cation and Anion01:18

    π Molecular Orbitals of the Allyl Cation and Anion

    An allyl group is a three-carbon conjugated system where the sp³-hybridized allylic carbon is bonded to a CH=CH2 group via a single bond. Allyl anions can be obtained by treating propene with a strong base that can deprotonate methyl groups. Allyl cations are formed as intermediates during substitution reactions involving allylic halides. In both cases, the hybridization of the allylic carbon changes from sp3 to sp2, giving rise to a carbon chain with three sp2-hybridized carbons, each with an...
    Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

    Crystal Field Theory - Tetrahedral and Square Planar Complexes

    Tetrahedral Complexes
    Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
    Molecular Geometry and Dipole Moments02:36

    Molecular Geometry and Dipole Moments

    The VSEPR theory can be used to determine the electron pair geometries and molecular structures as follows:
    Molecular Orbital Theory I02:35

    Molecular Orbital Theory I

    Overview of Molecular Orbital Theory
    MO Theory and Covalent Bonding02:40

    MO Theory and Covalent Bonding

    The molecular orbital theory describes the distribution of electrons in molecules in a manner similar to the distribution of electrons in atomic orbitals. The region of space in which a valence electron in a molecule is likely to be found is called a molecular orbital. Mathematically, the linear combination of atomic orbitals (LCAO) generates molecular orbitals. Combinations of in-phase atomic orbital wave functions result in regions with a high probability of electron density, while...