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Updated: Jun 28, 2026

Non-aqueous Electrode Processing and Construction of Lithium-ion Coin Cells

Non-aqueous Electrode Processing and Construction of Lithium-ion Coin Cells

Published on: February 1, 2016

Liquid ion-exchange membrane electrode for lithium.

W A Hildebrandt¹, K H Pool

¹Chemistry Department, Washington State University, Pullman, WA 99163, U.S.A.

|June 1, 1976

Summary

This summary is machine-generated.

A novel lithium-selective electrode using n-decanol as the liquid membrane and exchanger offers high selectivity and a broad linear response range. This sensor provides performance comparable to existing glass electrodes for univalent cations.

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Area of Science:

Electrochemistry
Analytical Chemistry
Materials Science

Background:

Accurate detection of lithium ions is crucial in various chemical and biological applications.
Existing lithium-ion selective electrodes often face challenges with selectivity and response range.

Purpose of the Study:

To develop a new electrode with enhanced selectivity for lithium ions over other alkali metals.
To characterize the performance of the novel n-decanol-based sensor.

Main Methods:

Fabrication of a liquid membrane electrode utilizing n-decanol as both the membrane solvent and ion exchanger.
Electrochemical measurements to assess the electrode's response and selectivity.

Main Results:

The developed electrode demonstrated a linear, near-Nernstian response over more than three orders of magnitude.
Achieved selectivity for lithium ions comparable to the established LAS 15-25 glass univalent-cation electrode.

Conclusions:

N-decanol serves as an effective component for creating highly selective lithium-ion sensors.
The new electrode offers a promising alternative for lithium ion detection with excellent performance characteristics.