PVC ion-selective electrodes based on calcium bis-[dialkyl- and di-(4-alkylphenyl) phosphates] and mixed solvent...

PVC calcium ion-selective electrodes based on either calcium bis-di(n-decyl)phosphate or calcium bis-di[4-(1,1,3,3-tetramethylbutyl)phenyl]phosphate with various solvent mediators (alone or in pairs) have been evaluated with particular respect to interference from Na(+), K(+), Mg(2+), Sr(2+), Ba(2+), Mn(2+), Cu(2+), Ni(2+) and Zn(2+) ions. PVC calcium ion-selective electrodes based on calcium bis-di[4-(n-octyl)phenyl]phosphate with varied amounts of decan-l-ol plus di-n-octyl phenylphosphonate showed a continuous gradation in selectivity coefficients on going from a high fraction of decan-l-ol to a high fraction of the second mediator. Thus, k(pot)(Ca,Mg) changed from 1.6 for an electrode based exclusively on decan-l-ol to 4.9 x 10(-4) for one based completely on di-n-octyl phenylphosphonate. The corresponding k(pot)(Ca,Na) values were 7.0 x 10(-2) and 1.1 x 10(-3).