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Published on: July 23, 2014
Application of personal computers in the analytical laboratory-III ASV analysis
D Kaplan1, D Raphaeli, S Ben-Yaakov
1Department of Electrical and Computer Engineering, Ben-Gurion University of the Negev, Beer Sheba, 84105, Israel.
This study presents an automated system for anodic stripping voltammetry (ASV) analysis using a personal computer. The developed software enables efficient data processing and accurate peak evaluation, even with noisy or complex samples.
Area of Science:
- Analytical Chemistry
- Electrochemistry
Background:
- Anodic stripping voltammetry (ASV) is a sensitive electrochemical technique.
- Automation of ASV analysis and data processing can improve efficiency and accuracy.
- Handling complex matrices and noise is a challenge in ASV.
Purpose of the Study:
- To develop an automated system for ASV analysis and data processing.
- To implement robust peak evaluation methods for distorted peaks.
- To apply the system to real-world environmental samples.
Main Methods:
- Interfacing a polarograph with a personal computer.
- Developing a software package in SUPER BASIC with graphic routines.
- Implementing automatic data processing including baseline correction and Gaussian fitting for peak analysis.
Main Results:
- The developed software allows for manual, interactive, and automatic data processing.
- Automatic peak evaluation using Gaussian fitting is insensitive to noise.
- The system is successfully used for routine analysis of treated wastewater and irrigated soils.
Conclusions:
- The automated ASV system provides a flexible and efficient platform for environmental analysis.
- The implemented data processing methods enhance accuracy in complex matrices.
- Interactive features are crucial for analyzing distorted peaks in real samples.
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