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Related Concept Videos

Voltammetry: Stripping Methods01:13

Voltammetry: Stripping Methods

Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used to determine trace amounts of analytes in solution. These methods involve applying a potential to an electrode and measuring the resulting current.
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
Voltammetric Techniques: Linear-Scan (E vs Time)01:12

Voltammetric Techniques: Linear-Scan (E vs Time)

Polarography is a classical voltammetric technique used to analyze electrochemical reactions. This method applies a linear potential sweep to a dropping mercury electrode (DME), and the resulting current is measured. A dropping mercury electrode is commonly used as the working electrode in polarography. It consists of a capillary tube filled with mercury, where the tiny droplet forms at the tip. This droplet continuously drops from the capillary, creating a new electrode surface for each...
Voltammetry: Overview01:20

Voltammetry: Overview

Voltammetry is an electroanalytical technique in which the current flowing through an electrochemical cell is measured as a function of applied potential, typically under conditions of concentration polarization. The technique provides valuable information about redox-active species, and the current response is plotted as a voltammogram.
A voltammetric cell uses three electrodes: a working electrode, a reference electrode, and an auxiliary electrode. The redox reactions occur in the working...
Voltammetric Techniques: Pulse Voltammetry01:17

Voltammetric Techniques: Pulse Voltammetry

Differential-pulse voltammetry (DPV) is a type of voltammetry that involves applying a series of voltage pulses to an electrochemical cell while measuring the resulting current. In DPV, the differential pulse or small potential pulses are superimposed on a linear potential sweep. The magnitude of these pulses is typically small, often in the millivolt range. Each voltage pulse lasts a short duration, usually in the order of a few milliseconds, and is applied at regular intervals along the...
Voltammetric Techniques: Cyclic Voltammetry01:10

Voltammetric Techniques: Cyclic Voltammetry

Cyclic voltammetry (CV) is an electrochemical technique used to investigate the redox properties of a chemical species. It involves measuring the current response of an electrochemical cell as a function of the applied potential. The setup for cyclic voltammetry typically consists of a working electrode, a reference electrode, and a counter electrode—all immersed in an electrolyte solution. The working electrode is where the redox reaction of interest occurs, while the reference electrode...
Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at the...

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Hollow Microneedle-based Sensor for Multiplexed Transdermal Electrochemical Sensing
08:19

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Published on: June 1, 2012

Screen-printed voltammetric sensor for TNT.

J Wang1, F Lu, D Macdonald

  • 1Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, NM 88003, USA.

Talanta
|October 31, 2008
PubMed
Summary
This summary is machine-generated.

New disposable sensors offer rapid, selective detection of 2,4,6-trinitrotoluene (TNT) in environmental samples. These screen-printed carbon electrodes provide on-site screening with a low detection limit, aiding in pollution monitoring.

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Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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Published on: January 30, 2015

Area of Science:

  • Electrochemistry
  • Environmental Science
  • Sensor Technology

Background:

  • 2,4,6-trinitrotoluene (TNT) is a hazardous explosive compound requiring sensitive detection methods.
  • Existing methods for TNT detection can be complex and unsuitable for rapid on-site environmental screening.
  • Development of cost-effective and disposable sensors is crucial for widespread environmental monitoring.

Purpose of the Study:

  • To develop and optimize disposable voltammetric sensors for the detection of 2,4,6-trinitrotoluene (TNT).
  • To evaluate the performance of screen-printed carbon electrodes for environmental TNT analysis.
  • To establish a sensitive and selective method for on-site TNT screening.

Main Methods:

  • Fabrication and comparison of thick-film screen-printed carbon electrodes using various inks.
  • Optimization of experimental variables for square-wave voltammetry.
  • Testing sensor performance with untreated environmental samples.

Main Results:

  • Achieved a detection limit of 200 ppb for TNT.
  • Demonstrated a wide linear range for TNT quantification.
  • Exhibited high selectivity for TNT in complex environmental matrices due to the unique nitro group electrochemistry.

Conclusions:

  • Disposable screen-printed carbon electrodes are effective for sensitive and selective TNT detection.
  • The developed voltammetric method facilitates rapid on-site environmental screening of TNT.
  • Single-use sensor strips offer a practical solution for pollution monitoring and environmental safety assessments.