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Analysis of Volatile and Oxidation Sensitive Compounds Using a Cold Inlet System and Electron Impact Mass Spectrometry
Published on: September 5, 2014
Flow injection on-line electrothermal atomic absorption spectrometry.
E V Alonso1, A García de Torres, J M Pavón
1Department of Analytical Chemistry, Faculty of Sciences, University of Málaga, 29071 Málaga, Spain.
Continuous flow injection (FI) systems are now effectively coupled with electrothermal atomic absorption spectrometry (ETAAS) operations. This review covers 109 references on the development and expansion of flow injection–electrothermal atomic absorption spectrometry (FI-ETAAS) methodology.
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Area of Science:
- Analytical Chemistry
- Atomic Spectroscopy
- Separation Science
Background:
- Coupling continuous flow injection (FI) systems with discrete electrothermal atomic absorption spectrometry (ETAAS) presented significant challenges.
- Recent advancements have overcome previous limitations in integrating these techniques.
Purpose of the Study:
- To review the development and expansion of the flow injection–electrothermal atomic absorption spectrometry (FI-ETAAS) methodology.
- To consolidate recent progress in FI-ETAAS systems based on a review of 109 references.
Main Methods:
- Systematic literature review of 109 relevant publications.
- Categorization of selected FI-ETAAS systems based on their operational principles.
Main Results:
- Overcoming major hindrances in coupling continuous FI systems with discrete ETAAS operations.
- Identification and classification of various FI-ETAAS systems, including on-line preconcentration, separation, aerosol deposition, and in situ trapping techniques.
Conclusions:
- The integration of FI and ETAAS is now a well-established and expanding methodology.
- Diverse FI-ETAAS configurations offer versatile solutions for various analytical applications.