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Updated: Jun 28, 2026

High-Throughput Measurement and Classification of Organic P in Environmental Samples
Published on: June 8, 2011
Characterizing phosphorus in environmental and agricultural samples by 31P nuclear magnetic resonance spectroscopy
1Geological and Environmental Sciences Department, Stanford University, Stanford, CA 94305-2115, USA. bjcm@pangea.stanford.edu
Abstract:
Phosphorus nuclear magnetic resonance ((31)P-NMR) spectroscopy has advanced our knowledge of organic phosphorus (P) in soils and environmental samples more than any other technique. This paper reviews the use of (31)P-NMR spectroscopy for soil, water and other environmental samples. The requirements for a successful solid-state or solution (31)P-NMR experiment are described, including experimental set-up, sample preparation, extractants, experimental conditions, and post-experimental processing. Next, the literature on solid-state and solution (31)P-NMR spectroscopy in environmental samples is reviewed, including papers on: methods; P transformations; agricultural, forest and natural ecosystem soil studies; humic acid and particle size separations; manure, compost and sludge studies; and water research, including freshwater, estuary and marine studies. Future research needs are also discussed as well as suggestions to improve results, such as increased standardization among research groups.
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