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Updated: Jun 28, 2026

Setup of Capillary Electrophoresis-Inductively Coupled Plasma Mass Spectrometry (CE-ICP-MS) for Quantification of Iron Redox Species (Fe(II), Fe(III))
Published on: May 4, 2020
Investigation of iron oxide nanoparticles by capillary zone electrophoresis
Natalia G Vanifatova1, Boris Ya Spivakov, Juergen Mattusch
1Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Kosygin Street 19, 117975 Moscow, Russia.
Abstract:
The electrophoretic behavior of gamma-Fe(2)O(3) nanoparticles was studied in aqueous solutions of Na(2)SO(4)-NaOH (pH 10.8) and of Na(2)SO(4)-Na(3)cit (pH 7.1) as running electrolytes. Two electrophoretic zones (smooth and with spikes) due to colloidal and suspended particles of approximately the same size range were formed during the runs. The suspension stability and size distribution were shown to depend on the composition of electrolyte used for dispersing the solids. The effects of electric field strength, injection time, injection pressure as well as sodium citrate concentration were studied and particle electrophoretic mobilities were calculated. Electron micrographs of particles studied were obtained. Preparation of reference samples based on the colloidal gamma-Fe(2)O(3) has been discussed.
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