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Updated: Jun 28, 2026

Calcium Carbonate Formation in the Presence of Biopolymeric Additives
Published on: May 14, 2019
Protonation of carbonate in aqueous tetraalkylammonium salts at 25 degrees C
Francesco Crea1, Concetta De Stefano, Antonio Gianguzza
1Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Salita Sperone 31, I-98166 Messina (Vill. S. Agata), Italy.
Abstract:
Protonation constants of carbonate were determined in tetramethylammonium chloride (Me(4)NCl(aq) 0.1=I/molkg(-1)=4) and tetraethylammonium iodide (Et(4)NI(aq) 0.1=I/molkg(-1)=1) by potentiometric ([H(+)]-glass electrode) measurements. Dependence of protonation constants on ionic strength was taken into account by modified specific ion interaction theory (SIT) and by Pitzer models. Literature data on the protonation of carbonate in NaCl(aq) (0.1=I/molkg(-1)=6) were also critically analysed. Both protonation constants of carbonate follow the trend Et(4)NI>Me(4)NCl>NaCl. An ion pair formation model designed to take into account the different protonation behaviours of carbonate in different supporting electrolytes was also evaluated.
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