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Colloids03:22

Colloids

Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
The Colloidal State01:29

The Colloidal State

The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...
Colloids and Suspensions01:17

Colloids and Suspensions

Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
Colloidal precipitates01:09

Colloidal precipitates

The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Coagulation01:06

Coagulation

Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...

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Related Experiment Video

Updated: Jun 28, 2026

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown
04:56

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown

Published on: June 27, 2025

Optical trapping forces for colloids at the oil-water interface.

Bum Jun Park1, Eric M Furst

  • 1Department of Chemical Engineering and Center for Molecular and Engineering Thermodynamics, University of Delaware, Newark, Delaware 19716, USA.

Langmuir : the ACS Journal of Surfaces and Colloids
|November 5, 2008
PubMed
Summary
This summary is machine-generated.

Optical trapping forces on dielectric spheres at oil-water interfaces were calculated. These forces, influenced by the three-phase contact angle, do not induce capillary interactions between particles.

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Optical Trapping of Nanoparticles
13:39

Optical Trapping of Nanoparticles

Published on: January 15, 2013

Related Experiment Videos

Last Updated: Jun 28, 2026

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown
04:56

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown

Published on: June 27, 2025

Optical Trapping of Nanoparticles
13:39

Optical Trapping of Nanoparticles

Published on: January 15, 2013

Area of Science:

  • Physics
  • Optical physics
  • Soft matter physics

Background:

  • Optical trapping is crucial for manipulating microparticles.
  • Understanding forces at interfaces is key for colloid science.
  • Dielectric spheres at liquid-liquid interfaces present unique interaction dynamics.

Purpose of the Study:

  • To calculate optical trapping forces on a dielectric sphere at a 2D oil-water interface.
  • To investigate the role of geometrical optics approximation (GOA) in predicting these forces.
  • To determine if calculated forces can induce capillary interactions and analyze the influence of the contact angle.

Main Methods:

  • Utilizing geometrical optics approximation (GOA) for force calculations.
  • Simulating optical trapping of a single dielectric sphere.
  • Comparing calculated lateral trapping forces with experimental data.
  • Analyzing radiation forces perpendicular to the interface.

Main Results:

  • Calculated lateral trapping forces align with experimental measurements.
  • Radiation forces perpendicular to the interface are insufficient to cause capillary interactions.
  • Optical trapping forces are dependent on the particle's three-phase contact angle.

Conclusions:

  • The GOA provides accurate predictions for lateral optical trapping forces at interfaces.
  • Optical trapping alone does not induce particle-particle capillary interactions at this interface.
  • The three-phase contact angle is a critical parameter influencing optical trapping forces at the oil-water interface.