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Chemoenzymatic synthesis of chiral 4,4'-bipyridyls and their metal-organic frameworks

Lenuta Sbircea1, Narain D Sharma, William Clegg

  • 1Centre for the Theory and Application of Catalysis, Queen's University Belfast, Belfast, Northern Ireland, UKBT9 5AG.

Chemical Communications (Cambridge, England)
|November 11, 2008
PubMed

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Prochirality02:05

Prochirality

The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...