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Related Concept Videos

¹H NMR of Labile Protons: Temporal Resolution01:10

¹H NMR of Labile Protons: Temporal Resolution

Protons bonded to heteroatoms such as nitrogen and oxygen exhibit a range of chemical shift values. This is due to the varying degree of hydrogen bonding between the proton and the heteroatom in other molecules. The extent of hydrogen bonding affects the electron density around the proton, thereby giving different chemical shift values for the protons in the proton NMR spectrum.
The –OH proton in alcohols typically appears in the range of δ 2 to 5 ppm but can vary depending on the specific...
2D NMR: Overview of Homonuclear Correlation Techniques01:16

2D NMR: Overview of Homonuclear Correlation Techniques

Homonuclear correlation spectroscopy (COSY) is a powerful technique used in Nuclear Magnetic Resonance (NMR) spectroscopy to study the correlations between nuclei of the same type within a molecule. It provides information about scalar couplings between adjacent nuclei, which helps determine connectivity and structural information. There are several COSY variants, each with its unique strengths and experimental parameters.
COSY90 is the standard two-dimensional (2D) COSY experiment that...
2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)01:19

2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)

Heteronuclear single-quantum correlation spectroscopy (HSQC) is a 2D NMR technique that reveals one-bond correlations between hydrogen and a heteronucleus. The HSQC experiment is similar to the heteronuclear correlation experiment (HETCOR) but is more sensitive. In the HSQC spectrum, the proton chemical shift is plotted on the horizontal F2 axis, while the 13C chemical shift is plotted on the vertical F1 axis. The corresponding proton and 13C spectra are also shown. The HSQC contour plot does...
2D NMR: Overview of Heteronuclear Correlation Techniques01:18

2D NMR: Overview of Heteronuclear Correlation Techniques

Heteronuclear correlation spectroscopy is an analytical technique that investigates the coupling between different types of nuclei, often a proton and an X-nucleus, such as carbon-13 or nitrogen-15. This method is commonly used in nuclear magnetic resonance (NMR) spectroscopy to gain insights into complex chemical compounds' structural and compositional aspects. A typical heteronuclear correlation spectrum displays X-nucleus chemical shifts on one axis and a proton spectrum on the other axis.
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution00:52

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution

At room temperature, the chair conformer of cyclohexane undergoes rapid ring flipping between two equivalent chair conformers at a rate of approximately 105 times per second. These two chair conformers are in equilibrium. The rapid ring flipping results in the interconversion of the axial proton to an equatorial proton and an equatorial to the axial proton. Such interconversions are too rapid and cannot be detected on the NMR timescale. Hence, the NMR spectrometer cannot distinguish between the...
Atomic Nuclei: Nuclear Spin State Population Distribution01:14

Atomic Nuclei: Nuclear Spin State Population Distribution

Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy spin-down state. As temperatures increase, the energy from thermal collisions distributes the spins more equally between the two states. The Boltzmann distribution equation gives the ratio of the number of spins predicted in the spin −½ (N−) and spin +½ (N+) states.

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Related Experiment Video

Updated: Jun 28, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

Joint temporal density measurements for two-photon state characterization.

Onur Kuzucu1, Franco N C Wong, Sunao Kurimura

  • 1Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Physical Review Letters
|November 13, 2008
PubMed
Summary
This summary is machine-generated.

We developed a new method to characterize two-photon quantum states using joint temporal correlations. This technique measures the time-energy entanglement of photon pairs, improving quantum state analysis.

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Last Updated: Jun 28, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

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Published on: June 8, 2018

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10:16

A Protocol for Real-time 3D Single Particle Tracking

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Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators
09:23

Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators

Published on: May 30, 2014

Area of Science:

  • Quantum Optics
  • Quantum Information Science
  • Photonics

Background:

  • Characterizing quantum states is crucial for quantum information processing.
  • Existing methods often focus on frequency-domain correlations.
  • Time-resolved measurements offer complementary insights into photonic entanglement.

Purpose of the Study:

  • To demonstrate a novel technique for characterizing two-photon quantum states.
  • To measure the joint temporal density of entangled photon pairs for the first time.
  • To explore the manipulation of frequency entanglement via pump bandwidth.

Main Methods:

  • Utilizing joint temporal correlation measurements.
  • Employing time-resolved single-photon detection with femtosecond up-conversion.
  • Generating photon pairs via ultrafast spontaneous parametric down-conversion under extended phase-matching.

Main Results:

  • Successfully measured the joint temporal density of a two-photon entangled state.
  • Observed clear time anti-correlation in coincident-frequency entangled photon pairs.
  • Demonstrated manipulation of frequency entanglement by varying pump bandwidth, producing a nearly unentangled state.
  • Predicted a heralded single-photon state purity of 0.88.

Conclusions:

  • The developed time-domain correlation technique provides a comprehensive characterization of photonic entanglement.
  • This method complements existing frequency-domain measurements.
  • The technique allows for the generation of high-purity heralded single-photon states.