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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique

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Microwave-assisted synthesis, characterization and biological activities of organotin (IV) complexes with some thio

Ran Vir Singh1, Pratibha Chaudhary, Shikha Chauhan

  • 1Department of Chemistry, University of Rajasthan, Jaipur 302004, India. rvsjpr@hotmail.com

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|November 26, 2008
PubMed

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...