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Updated: Jun 27, 2026

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts
Published on: February 7, 2017
Atmospheric chemistry of acetylacetone
Shouming Zhou1, Ian Barnes, Tong Zhu
1State Key Joint Laboratory for Environmental Simulation and Pollution Control, College of Environmental Science, Peking University, 100871 Beijing, China.
Abstract:
A kinetic study on the reactions of the OH radical and ozone with acetylacetone (AcAc) has been performed in a 1080 L quartz glass reaction chamber using in situ FTIR spectroscopy analysis. Temperature dependent rate coefficients for the reaction of AcAc with the OH radical were determined over the temperature range 285-310 K using the relative kinetic method. The following Arrhenius expression was derived: k = 3.35 x 10(-12) exp((983 +/- 130)/T) cm3 molecule(-1) s(-1), where the indicated error is the two least-squares deviation. A rate coefficient (in units of cm3 molecule(-1) s(-1)) of (1.03 +/- 0.31) x 10(-18) has been obtained at (298 +/- 3) K for the reaction of ozone with AcAc. A product investigation on the gas-phase reaction of OH radical with AcAc was conducted in a 405 L borosilicate glass chamber using in situ FTIR spectroscopy to monitor reactants and products. Methylglyoxal, acetic acid, peroxy acetic nitrate (PAN) were positively identified as products with molar yields of (20.8 +/- 4.5)%, (16.9 +/- 3.4)%, and (2.0 +/- 0.5)%, respectively. From the residual infrared spectrum the main products are attributed to 2,3,4-pentantrione (CH3-CO-CO-CO-CH3) and its hydrated analogue pentan-2,3-dione-4-diol (CH3-CO-CO-C(OH)2-CH3). Based on the observed products, a simplified mechanism for the reaction of the OH radical with AcAc is proposed.
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