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Related Concept Videos

Multiple Halogenation of Methyl Ketones: Haloform Reaction01:28

Multiple Halogenation of Methyl Ketones: Haloform Reaction

A method involving the transformation of methyl ketones to carboxylic acids using excess base and halogen is called the haloform reaction. It begins with the deprotonation of α hydrogen to form an enolate ion which reacts with the electrophilic halogen to give an α-halo ketone. The step continues until all the α protons are substituted to form a trihalomethyl ketone. The resulting molecule is unstable, and in the presence of a hydroxide base, it readily undergoes nucleophilic acyl substitution.
Acid-Catalyzed α-Halogenation of Aldehydes and Ketones01:21

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By replacing an α-hydrogen with a halogen, acid-catalyzed α-halogenation of aldehydes or ketones yields a monohalogenated product
In the first step of the mechanism, the acid protonates the carbonyl oxygen resulting in a resonance-stabilized cation, which subsequently loses an α-hydrogen to form an enol tautomer. The C=C bond in an enol is highly nucleophilic because of the electron-donating nature of the –OH group. Consequently, the double bond attacks an electrophilic halogen to form a...
Electrophilic Addition to Alkynes: Hydrohalogenation02:35

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Electrophilic addition of hydrogen halides, HX (X = Cl, Br or I) to alkenes forms alkyl halides as per Markovnikov's rule, where the hydrogen gets added to the less substituted carbon of the double bond. Hydrohalogenation of alkynes takes place in a similar manner, with the first addition of HX forming a vinyl halide and the second giving a geminal dihalide.
Anionic Chain-Growth Polymerization: Overview01:20

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
α-Halogenation of Carboxylic Acid Derivatives: Overview01:14

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Unlike aldehydes and ketones, carboxylic acids do not readily participate in α halogenation reactions via enols or enolate intermediates. However, α-halogenated acids are obtained through other methods. One of the approaches is the Hell–Volhard–Zelinsky (HVZ) reaction, wherein the carboxylic acid is treated with halogen in the presence of PBr3. It involves the conversion of acid to acid halide, which exists in equilibrium with its enol form. The enol attacks the electrophilic halogen to produce...

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The legendary Rome halo displays.

Walter Tape1, Eva Seidenfaden, Gunther P Können

  • 1University of Alaska, Department of Mathematics 6660, Fairbanks , Alaska 99775-6660, USA. ffwrt@uaf.edu

Applied Optics
|November 28, 2008
PubMed
Summary

Historical halo displays in Rome from 1629 and 1630 are re-examined. Documentation is insufficient to confirm rare halo phenomena like the 28-degree halo, though the displays remain significant for early atmospheric optics science.

Area of Science:

  • Atmospheric optics
  • Historical meteorology
  • Optical phenomena

Background:

  • The 1629 and 1630 Rome halo displays are historically significant in early halo research.
  • The 1629 display is often cited for a purported 28-degree circular halo.

Purpose of the Study:

  • To critically evaluate the documentation of the 1629 and 1630 Rome halo displays.
  • To ascertain the validity of reported rare halo phenomena, specifically the 28-degree halo.

Main Methods:

  • Analysis of seventeenth-century correspondence and publications.
  • Historical document review and interpretation.

Main Results:

  • The available documentation for both halo displays is found to be weak.

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  • Little evidence supports the existence of a 28-degree halo or other rare halos during these displays.
  • Conclusions:

    • The interpretations of the 1629 and 1630 Rome halo displays are not definitively supported by existing historical records.
    • Despite weak documentation, these displays were pivotal in the inception of modern halo science.