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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Synthesis and structural characterisation of a soluble, metastable indium(I) halide complex, [InBr(tmeda)]
Shaun P Green1, Cameron Jones, Andreas Stasch
1School of Chemistry, Monash University, Melbourne, P.O. Box 23, Victoria, 3800, Australia.
Chemical Communications (Cambridge, England)
|December 3, 2008
Abstract:
The first example of an indium(i) halide complex, [InBr(tmeda)], has been prepared by the reversible dissolution of InBr in a tmeda-toluene mixture. The structural characterisation of the metastable compound shows it to be monomeric with weak InIn interactions in the solid state. In solution, it decomposes to either InBr or [In2Br4(tmeda)2].
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