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Area of Science:

  • Environmental Science
  • Electrochemistry
  • Biotechnology

Background:

  • Ion exchange membranes in microbial electrolysis cells (MECs) increase costs and ohmic resistance.
  • Minimizing pH gradients is crucial for enhancing MEC performance and conversion rates.

Purpose of the Study:

  • To investigate the feasibility and performance of membraneless MECs for methane production.
  • To evaluate the impact of removing cation exchange membranes on ohmic resistance and current density.

Main Methods:

  • Operation of MECs without ion exchange membranes using plain graphite electrodes.
  • Monitoring methane production and current density under specific pH and organic loading conditions.
  • Comparison of performance metrics between membraneless and conventional MECs.

Main Results:

  • Membraneless MECs achieved higher current production (156 A m(-3)) compared to conventional MECs (66 A m(-3)).
  • Ohmic cell resistance was reduced by approximately 50% after membrane removal.
  • Methane was the primary energetic product, even under carbonate-limited and slightly acidic conditions (pH 6.1-6.2).

Conclusions:

  • Membraneless MECs offer a cost-effective alternative with improved efficiency for energy recovery.
  • Methane production is favored in membraneless MECs, posing challenges for pure hydrogen generation.
  • These systems show promise as a polishing step for anaerobic digester effluent treatment.