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High pressure Raman spectroscopic study of deuterated gamma-glycine
Ajay K Mishra1, Chitra Murli, Surinder M Sharma
1High Pressure Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085, India.
Abstract:
Raman spectroscopic investigations of deuterated gamma-glycine, carried out up to 21 GPa, indicate emergence of a new phase, which is similar to the delta-phase, reported to be formed from the undeuterated gamma-glycine at 3 GPa and the transformation to this phase is complete by 6 GPa. Observed pressure -induced variations in CD2 and N-D stretching modes indicate significant changes in the hydrogen-bonding interactions. Around approximately 15 GPa, splitting of CD2 and C-C stretching modes and discontinuous changes in the slope of CO2 and N-D stretching modes indicate another structural rearrangement across this pressure. The Raman spectra of retrieved phase at ambient conditions suggest that it may be a layered structure similar to the zeta-phase reported to be formed on decompression of the nondeuterated delta-glycine.
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