Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Revealing the Innate Subnanometer Porous Structure of Carbon Nanomembranes with Molecular Dynamics Simulations and Highly-Charged Ion Spectroscopy.

The journal of physical chemistry. C, Nanomaterials and interfaces·2026
Same author

Cysteine-Targeting Gd-Based Spin Label and Its Application in Electron Paramagnetic Resonance Spectroscopy.

Bioconjugate chemistry·2025
Same author

ih-RIDME: a pulse EPR experiment to probe the heterogeneous nuclear environment.

Magnetic resonance (Gottingen, Germany)·2025
Same author

Electron-spin decoherence in trityl radicals in the absence and presence of microwave irradiation.

Magnetic resonance (Gottingen, Germany)·2025
Same author

Advances in carbon nanomembranes for separation: from free-standing films to composite structures.

Nanoscale·2025
Same author

Measuring Nanometer Distances in Proteins and Rigid Rulers between <sup>19</sup>F and Gd<sup>3+</sup> by Integration of <sup>19</sup>F-ENDOR Signal Intensities.

Journal of the American Chemical Society·2025
Same journal

Stability constants of lanthanide-nitrate complexes in aqueous solutions: a theoretical study.

Physical chemistry chemical physics : PCCP·2026
Same journal

Lead-free Cs<sub>3</sub>MnCl<sub>5</sub> and CsMnCl<sub>3</sub> crystals: rapid on-chip crystallization, phase transition and fluorescence sensing applications.

Physical chemistry chemical physics : PCCP·2026
Same journal

F-Interstitial passivation preserves host-like optoelectronic properties in <sup>229</sup>Th:YLF nuclear-clock platforms.

Physical chemistry chemical physics : PCCP·2026
Same journal

Structural trends of tryptophan dimer: hydrogen bonding <i>versus</i> π-stacking from an energy decomposition analysis perspective.

Physical chemistry chemical physics : PCCP·2026
Same journal

Achieving high thermoelectric performance in Sb<sub>2</sub>Se<sub>3</sub>-alloyed GeTe through synergistic optimization of electrical and thermal transport.

Physical chemistry chemical physics : PCCP·2026
Same journal

Ultraviolet perfect absorption leveraging bound states in the continuum in an Al/SiO<sub>2</sub> hybrid system.

Physical chemistry chemical physics : PCCP·2026
See all related articles

Related Experiment Video

Updated: Jun 27, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Fully cross-linked and chemically patterned self-assembled monolayers.

André Beyer1, Adelheid Godt, Ihsan Amin

  • 1Universität Bielefeld, Fakultät für Physik, Physik Supramolekularer Systeme, Postfach 10 01 31, 33501, Bielefeld, Germany. beyer@physik.uni-bielefeld.de

Physical Chemistry Chemical Physics : PCCP
|December 9, 2008
PubMed
Summary
This summary is machine-generated.

Chemically patterned, mechanically stable monolayers are created using electron beam lithography and thiol exchange on aromatic self-assembled monolayers (SAMs). This technique enables site-selective functionalization for advanced material applications.

More Related Videos

Creating Two-Dimensional Patterned Substrates for Protein and Cell Confinement
08:36

Creating Two-Dimensional Patterned Substrates for Protein and Cell Confinement

Published on: September 6, 2011

Antifouling Self-assembled Monolayers on Microelectrodes for Patterning Biomolecules
10:27

Antifouling Self-assembled Monolayers on Microelectrodes for Patterning Biomolecules

Published on: August 25, 2009

Related Experiment Videos

Last Updated: Jun 27, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Creating Two-Dimensional Patterned Substrates for Protein and Cell Confinement
08:36

Creating Two-Dimensional Patterned Substrates for Protein and Cell Confinement

Published on: September 6, 2011

Antifouling Self-assembled Monolayers on Microelectrodes for Patterning Biomolecules
10:27

Antifouling Self-assembled Monolayers on Microelectrodes for Patterning Biomolecules

Published on: August 25, 2009

Area of Science:

  • Materials Science
  • Surface Chemistry
  • Nanotechnology

Background:

  • Self-assembled monolayers (SAMs) are crucial for surface functionalization.
  • Creating mechanically stable and chemically patterned SAMs presents a significant challenge.
  • Existing methods often lack the precision for complex chemical patterning.

Purpose of the Study:

  • To develop a method for fabricating mechanically stable, chemically patterned SAMs.
  • To demonstrate the versatility of the technique for creating complementary patterns.
  • To validate the chemical functionality of the patterned monolayers.

Main Methods:

  • Spatially resolved chemical lithography using electron beam exposure.
  • Sequential cross-linking and molecular exchange of aromatic SAMs.
  • Characterization using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM).

Main Results:

  • Successfully fabricated mechanically stable SAMs with defined chemical patterns.
  • Demonstrated precise control over chemical heterogeneity within the monolayer.
  • Confirmed the kinetics of thiol exchange and the stability of cross-linked regions.
  • Showcased site-selective derivatization, confirming monolayer functionality.

Conclusions:

  • The combined lithography and cross-linking approach provides robust chemical patterning of SAMs.
  • This method offers a versatile platform for creating complex surface architectures.
  • The resulting patterned SAMs are suitable for site-specific chemical modifications and applications.