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Bridged triphenylamine-based dendrimers: tuning enhanced two-photon absorption performance with locked molecular
Zhen Fang1, Tang-Lin Teo, Liping Cai
1Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
Organic Letters
|December 11, 2008
Abstract:
Triphenylamine derivatives bridged by methylene units afford a near planar molecular platform in a series of one dimer and two oligomers exhibiting increased structural rigidity compared to that of their parent triphenylamines. This series of dendrimers show significantly enhanced two-photon absorptions that are up to 3-fold that of triphenylamines with similar molecular size and structure.

