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Organic dyes containing furan moiety for high-performance dye-sensitized solar cells

Jiann T Lin1, Pin-Cheng Chen, Yung-Sheng Yen

  • 1Institute of Chemistry, Academia Sinica, Taipei, Taiwan 115. jtlin@sinica.edu.tw

Organic Letters
|December 11, 2008
PubMed

Abstract:

New metal-free dyes with a furan moiety in the conjugated spacer between the arylamine donor and the 2-cyanoacrylic acid acceptor have been synthesized, and high efficiency dye-sensitized solar cells were fabricated using these molecules as light-harvesting sensitizers.

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.

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