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Updated: Jun 26, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
Double photoionization of thiophene and bromine-substituted thiophenes
P Linusson1, L Storchi, F Heijkenskjöld
1Department of Physics and Material Sciences, Uppsala University, Box 530, SE-751 21 Uppsala, Sweden.
Abstract:
We report the double photoionization spectra of thiophene, 3-bromothiophene, and 3,4-dibromothiophene using a coincidence spectroscopy technique based on electron time-of-flight measurements. Spectra have been recorded between the onset and 40.814 eV using He IIalpha radiation. The He I photoelectron spectrum of 3,4-dibromothiophene has also been measured. All the spectra have been analyzed and interpreted in detail on the basis of theoretical simulations from accurate Green's function calculations.
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