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Chelation-assisted carbon-halogen bond activation by a rhodium(I) complex

Shanshan Chen1, Yongxin Li, Jing Zhao

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.

Inorganic Chemistry
|December 25, 2008
PubMed
Summary

Rhodium complexes activate C-X bonds for C-H activation, forming cationic monohalide and neutral dihalide complexes. Dihalide complexes catalyze alkyne dimerization, while monohalides are inactive.

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