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A unique chair-shaped hexanuclear Cu(I) metallamacrocyclic C2H4 adduct encapsulating a BF4- anion

Masahiko Maekawa1, Atsuhiro Nabei, Toshi Tominaga

  • 1Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan. maekawa@rist.kindai.ac.jp

Dalton Transactions (Cambridge, England : 2003)
|January 6, 2009
PubMed
Summary

Researchers self-assembled three novel copper(I)-ethylene adducts using 4-(2-pyridyl)pyrimidine. The study demonstrated the crucial roles of both anion and solvent in the formation of these copper complexes.

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