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Updated: Jun 26, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Published on: October 3, 2014
A phosphorus analogue of Bis(eta4-cyclobutadiene)iron(0)
Robert Wolf1, J Chris Slootweg, Andreas W Ehlers
1Department of Organic and Inorganic Chemistry, Faculty of Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands.
Abstract:
P makes it possible: The convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(eta(4)-P(2)C(2)tBu(2))(2)] (see structure) suggests that the elusive all-carbon complex [Fe(eta(4)-C(4)H(4))(2)] is a viable synthetic target.
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