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Syntheses, Crystallization, and Spectroscopic Characterization of 3,5-Lutidine N-Oxide Dehydrate
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Crystallochemical formula as a tool for describing metal-ligand complexes - a pyridine-2,6-dicarboxylate example

Viktor N Serezhkin1, Anna V Vologzhanina, Larisa B Serezhkina

  • 1Samara State University, Ac. Pavlov St. 1, Samara 443011, Russian Federation.

Acta Crystallographica. Section B, Structural Science
|January 22, 2009
PubMed

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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