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Synthesis and spectral characteristics of two novel intramolecular charge transfer fluorescent dyes
Shengmei Song1, Dong Ju, Junfen Li
1Research Center of Environmental Science and Engineering, Department of Chemistry, Shanxi University, Shanxi 030006, PR China.
Abstract:
The synthesis and absorption/fluorescence properties of two novel intramolecular charge transfer (ICT) compounds of (fluorene-2-yl)-(9-ethylcarbazole-3-yl) ketene and 1-phenyl-3-(fluorenone-2-yl)-5-(9-ethylcarbazole-3-yl)-2-pyrazoline were reported. The primary structure of the target compounds was characterized by IR and (1)H NMR. The systems contained a fluorenone or a propenon group as an electron acceptor (A) and an N-ethylcarbazole and a pyrazoline group as electron donors (D). From the emissive properties it was concluded that the electronic coupling between D and A was sufficient to allow charge transfer in these molecules. The ICT maximal emission displayed a large wavelength shift and Stokes shifts increased in response to the increase of the solvent polarity. The highly solvatochromic properties made the two compounds of great interest as new classes of fluorescent probes, electroluminescent and electrofax materials.
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