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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Cation-pi controlled solid-state photodimerization of 4-azachalcones

Shinji Yamada1, Yoko Tokugawa

  • 1Department of Chemistry, Faculty of Science, Ochanomizu University, Bunkyo-ku, Tokyo 112-8610, Japan.

Journal of the American Chemical Society
|January 29, 2009
PubMed
Summary

This study introduces cation-pi interactions to control solid-state photodimerization of alkenes. This method enhances stereoselective cyclobutane dimer formation, offering a novel approach for alkene transformations.

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