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A luminescent microporous metal-organic framework for the fast and reversible detection of high explosives
Anjian Lan1, Kunhao Li, Haohan Wu
1Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China.
Abstract:
Sensors and sensitivity: A highly luminescent microporous metal-organic framework, [Zn(2)(bpdc)(2)(bpee)] (bpdc = 4,4'-biphenyldicarboxylate; bpee = 1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).
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