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Sequential Application of Glass Coverslips to Assess the Compressive Stiffness of the Mouse Lens: Strain and Morphometric Analyses
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Spatiotemporal structures in aging and rejuvenating glasses.

Peter G Wolynes1

  • 1Departments of Physics and Chemistry and Biochemistry, Center for Theoretical Biological Physics, University of California at San Diego, La Jolla, CA 92093, USA. pwolynes@ucsd.edu

Proceedings of the National Academy of Sciences of the United States of America
|February 4, 2009
PubMed
Summary

Aging and rejuvenating glasses exhibit complex structures due to mobility dynamics. Combining theories explains these changes, with rejuvenation showing flame-like fronts driven by mobility propagation.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Glass Science

Background:

  • Aging and rejuvenation in glasses involve complex spatiotemporal structure development.
  • Understanding these structures requires analyzing the interplay between mobility generation and transport.

Purpose of the Study:

  • To theoretically model and explain the complex spatiotemporal structures formed during glass aging and rejuvenation.
  • To investigate the role of mobility generation and transport in these structural changes.

Main Methods:

  • Combined random first-order transition theory (RFOT) for activated events with mode coupling theory (MCT).
  • Applied these theories in an inhomogeneous setting to account for spatial variations.
  • Utilized concepts from combustion theory to analyze the propagation of enhanced mobility fronts.

Main Results:

  • Mobility transport has modest effects on the time course of glass aging.
  • Glass rejuvenation is significantly impacted by the propagation of enhanced mobility fronts, resembling flame propagation.
  • The speed of these rejuvenation fronts can be estimated using combustion theory principles.

Conclusions:

  • The interplay between activated reconfiguration events and mobility transport governs glass aging and rejuvenation structures.
  • Rejuvenation exhibits distinct, flame-like propagation dynamics driven by mobility fronts.
  • Combustion theory provides a useful framework for understanding rejuvenation fronts and diluent uptake in glasses.