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Updated: Jun 25, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis of cyclopentadienyl ruthenium complexes bearing pendant chelating picolinates through an electrophilic
Craig Streu1, Patrick J Carroll, Rakesh K Kohli
1Department of Chemistry, University of Pennsylvania, 231 South 34 Street, Philadelphia, PA, 19104 (USA).
Abstract:
This note reports the facile synthesis of two ruthenium cyclopentadienyl half-sandwich complexes functionalized with coordinating alpha-picolinates. The synthetic approach involves the (eta(5)-chloromethylcyclopentadienyl)(eta(6)-benzene)ruthenium(II) cation as a useful common building block for cyclopentadienyl complexes bearing anchored ligands.
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