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Synthesis of thermally stable extra-large pore crystalline materials: a uranyl germanate with 12-ring channels
Chia-Hui Lin1, Ray-Kuang Chiang, Kwang-Hwa Lii
1Department of Chemistry, National Central University, Jhongli, Taiwan 320, ROC.
Journal of the American Chemical Society
|February 10, 2009
Abstract:
A thermally stable extra-large pore uranyl germanate is synthesized under high-temperature, high-pressure hydrothermal conditions at 585 degrees C and 150 MPa. The structure contains U(6+)O(6) tetragonal bipyramids which are interconnected by digermanate groups to form a 3D framework with 12-ring pore openings.
